Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
13466-78-9	3-Carene	90-96%	236-719-3
138-86-3	dipenteen	1-2%	205-341-0
127-91-3	pin-2(10)-een	0-1.5%	204-872-5
99-86-5	p-mentha-1,3-dieen	0-0.5%	202-795-1

Section 3 - Hazards Identification

Not available. Appearance: clear colorless to light amber liquid. Flash Point: 45 deg C.
Not available.
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: May cause eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through the skin. May cause sensitization by skin contact.
Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Not available.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. get medical aid.
Skin: get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable liquid and vapor.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 45 deg C ( 113.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool.

Section 7 - Handling and Storage

Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage: Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Flammables-area.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
3-Carene	20 ppm TWA (listed under turpentine and selected monoterpenes)	none listed	none listed
dipenteen	none listed	none listed	none listed
pin-2(10)-een	20 ppm TWA (listed under turpentine and selected monoterpenes)	none listed	none listed
p-mentha-1,3-dieen	none listed	none listed	none listed

OSHA Vacated PELs: 3-Carene: No OSHA Vacated PELs are listed for this chemical. dipenteen: No OSHA Vacated PELs are listed for this chemical. pin-2(10)-een: No OSHA Vacated PELs are listed for this chemical. p-mentha-1,3-dieen: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Not available.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: clear colorless to light amber
Odor: turpentine
pH: Not available.
Vapor Pressure: 16mmHg @50 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 166 - 170 deg C @760mmHg
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:0.863
Molecular Formula:C10H16
Molecular Weight:136.23

Section 10 - Stability and Reactivity

Chemical Stability: Not available.
Conditions to Avoid: Incompatible materials, ignition sources, exposure to air.
Incompatibilities with Other Materials: Strong oxidizing agents, mineral acids.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information

RTECS#:      
CAS# 13466-78-9: FH8400000      
CAS# 138-86-3: OS8100000      
CAS# 127-91-3: DT5077000      
CAS# 99-86-5: OS8060000
LD50/LC50:
CAS# 13466-78-9:
     Draize test, rabbit, skin: 500 mg/24H;
     Inhalation, mouse: LC50 = 49000 mg/m3;
     Oral, rat: LD50 = 4800 mg/kg;
.

CAS# 138-86-3:
     Draize test, rabbit, skin: 500 mg/24H Moderate;
     Inhalation, mouse: LC50 = 67500 mg/m3;
     Oral, mouse: LD50 = 5550 uL/kg;
     Oral, rat: LD50 = 5300 mg/kg;
.

CAS# 127-91-3:
     Draize test, rabbit, skin: 500 mg/24H Moderate;
     Inhalation, mouse: LC50 = 20000 mg/m3;
     Oral, rat: LD50 = 4700 mg/kg;
.

CAS# 99-86-5:
     Draize test, rabbit, skin: 15%/24H Mild;
     Oral, rat: LD50 = 1680 mg/kg;
.

Carcinogenicity:
CAS# 13466-78-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 138-86-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 127-91-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 99-86-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	TERPENE HYDROCARBONS, N.O.S.	No information available.
Hazard Class:	3
UN Number:	UN2319
Packing Group:	III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 13466-78-9 is listed on the TSCA inventory.
     CAS# 138-86-3 is listed on the TSCA inventory.
     CAS# 127-91-3 is listed on the TSCA inventory.
     CAS# 99-86-5 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 13466-78-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 138-86-3 can be found on the following state right to know lists: New Jersey.
     CAS# 127-91-3 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 99-86-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI
Risk Phrases:
     R 10 Flammable.
     R 38 Irritating to skin.
     R 43 May cause sensitization by skin contact.
     R 52/53 Harmful to aquatic organisms, may cause long-term adverse
     effects in the aquatic environment.

Safety Phrases:
     S 16 Keep away from sources of ignition - No smoking.
     S 24 Avoid contact with skin.
     S 37 Wear suitable gloves.

WGK (Water Danger/Protection)
     CAS# 13466-78-9: No information available.
     CAS# 138-86-3: No information available.
     CAS# 127-91-3: No information available.
     CAS# 99-86-5: No information available.
Canada - DSL/NDSL
     CAS# 13466-78-9 is listed on Canada's DSL List.
     CAS# 138-86-3 is listed on Canada's DSL List.
     CAS# 127-91-3 is listed on Canada's DSL List.
     CAS# 99-86-5 is listed on Canada's DSL List.
Canada - WHMIS
     WHMIS: Not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 138-86-3 is listed on the Canadian Ingredient Disclosure List.
     CAS# 127-91-3 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 4/03/2003
Revision #1 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.